| Name: | Oneeq19a - Compressibility factor from the RK equation - three solutions | ||
| Source: | Cutlip, M. B. and Shacham, M, Problem Solving in Chemical | ||
| Engineering with Numerical Methods (2nd Ed), Prentice Hall Inc., | |||
| Reference/s | |||
| Model: | 1 implicit equation, indep. variable name: z | ||
| Average difficulty level | |||
| Constraints: z>0 | |||
| Discontinuities: none in the range of interest | |||
| Initial range: zmin=-0.5, zmax=1.2 | |||
| Solved by | Shacham, M., POLYMATH 5.1, build 19, April 1, 2001 | ||
| Model Eqs. | Compressibility factor from the RK equation - three solutions |POLVER05_1 | ||
| f(z)=z^3-z^2-Q*z-r # | |||
| P = 200 # | |||
| Pc=33.5 # | |||
| T= 631*2 # | |||
| Tc=126.2 # | |||
| Pr=P/Pc # | |||
| Tr=T/Tc # | |||
| Asqr=0.4278*Pr/(Tr^2.5) # | |||
| B=0.0867*Pr/Tr # | |||
| Q=B^2+B-Asqr # | |||
| r=Asqr*B # | |||
| p=(-3*Q-1)/3 # | |||
| q=(-27*r-9*Q-2)/27 # | |||
| R=(p/3)^3+(q/2)^2 # | |||
| V=if(R>0)then((-q/2+sqrt(R))^(1/3))else(0) # | |||
| WW=if(R>0)then(-q/2-sqrt(R))else(0) # | |||
| psi1 = if(R<0)then(arccos(sqrt((q^2/4)/(-p^3/27))))else(0) # | |||
| W = if(R>0)then(sign(WW)*(abs(WW))^(1/3))else(0) # | |||
| z1 = if(R<0)then(2*sqrt(-p/3)*cos((psi1/3)+2*3.1416*0/3)+1/3)else(0) # | |||
| z2 = if(R<0)then(2*sqrt(-p/3)*cos((psi1/3)+2*3.1416*1/3)+1/3)else(0) # | |||
| z3 = if(R<0)then(2*sqrt(-p/3)*cos((psi1/3)+2*3.1416*2/3)+1/3)else(0) # | |||
| z0=if(R>0)then(V+W+1/3)else(0) # | |||
| z(min)=-.5, z(max)=1.2 | |||
| Variable/function values | Variable | Value |
|
| z | 0.35 |
|
|
| P | 200 | ||
| Pc | 33.5 | ||
| T | 1262 | ||
| Tc | 126.2 | ||
| Pr | 5.970149254 | ||
| Tr | 10 | ||
| Asqr | 0.008076552 | ||
| B | 0.051761194 | ||
| Q | 0.046363864 | ||
| r | 0.000418052 | ||
| p | -0.379697197 | ||
| q | -0.089946747 | ||
| R | -4.83753E-06 | ||
| V | 0 | ||
| WW | 0 | ||
| psi1 | 0.048870067 | ||
| W | 0 | ||
| z1 | 1.044760488 | ||
| z2 | -0.032420632 | ||
| z3 | -0.012336754 | ||
| z0 | 0 | ||
| Root1 | Variable | Value |
|
| z | -0.03241692071380 |
|
|
| P | 200 | ||
| Pc | 33.5 | ||
| T | 1262 | ||
| Tc | 126.2 | ||
| Pr | 5.970149254 | ||
| Tr | 10 | ||
| Asqr | 0.00807655154040 | ||
| B | 0.05176119402990 | ||
| Q | 0.04636386369680 | ||
| r | 0.00041805195140 | ||
| p | -0.37969719703020 | ||
| q | -0.08994674725770 | ||
| R | -0.00000483752560 | ||
| V | 0.00000000000000 | ||
| WW | 0.00000000000000 | ||
| psi1 | 0.048870067 | ||
| W | 0.00000000000000 | ||
| z1 | 1.044760488 | ||
| z2 | -0.032420632 | ||
| z3 | -0.012336754 | ||
| z0 | 0.00000000000000 | ||
| Root2 | Variable | Value |
|
| z | -0.01234360708030 |
|
|
| (The other variables have the same value as in Root1) | |||
| Root3 | Variable | Value |
|
| z | 1.04476050281300 |
|
|
| (The other variables have the same value as in Root1) | |||
| Function plot | |||