Problem 1(a) - Molar Volume and Compress... Van Der Waals f(V)=(P+a/(V^2))*(V-b)-R*T P=56 R=0.08206 T=450 Tc=405.5 Pc=111.3 Pr=P/Pc a=27*(R^2*Tc^2/Pc)/64 b=R*Tc/(8*Pc) Z=P*V/(R*T) V(min)=0.4, V(max)=1